Affiliation:
1. Eidgenössische Technische Hochschule
Abstract
In a case study, the mechanism of decomposition of diazonium ions in solution is discussed; the reasonable mechanism brought forward in 1940 was not refuted until 1973, in spite of experimental results published in 1952 that were not consistent with the proposed mechanism. A new mechanistic hypothesis, mentioned in the literature in 1973, was in contradiction to the paradigm that nitrogen molecules do not react with organic reagents in solution. After a psychologically explainable crisis the new hypothesis was tested experimentally and the paradigm mentioned was falsified for this case. In the analysis it is shown that Pop-perian logic was commingled with Kuhn’s cycle of normal science, crisis, and revolution, as well as with a psychological barrier. Joint investigations of modern problems by chemists and philosophers of science are encouraged because they may elucidate how progress in scientific discoveries takes place at the present time.
Subject
History and Philosophy of Science,Multidisciplinary