Enhancement of nuclear radiation shielding properties of silicone rubber with γ‐ray irradiation induced graphene oxide modified carbonyl iron powder hybrid fillers

Author:

Sun Xiaoyi1,Meng Xianfang2,Dai Pei12ORCID,Xu Riwei1,Cheng Anren2,Guo Yueying2,Jiao Yang2,Lu Yongjun2,Wang Liancai2

Affiliation:

1. State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology Beijing China

2. Beijing Key Laboratory of Radiation Advanced Materials Beijing Research Center for Radiation Application Beijing China

Abstract

AbstractIn this study the graphene oxide modified carbonyl iron (GO‐CI) was prepared by γ‐ray irradiation, which was added to silicone rubber composites to enhance the nuclear radiation shielding performances. X‐ray diffraction (XRD) characterization result showed the structure and morphology of the obtained GO‐CI nanocomposites. The mixture of GO/CI and the hybrid GO‐CI were individually incorporated into the vinyl‐terminated polydimethylsiloxane (Vi‐PDMS) to prepare referenced SR/GO/CI and SR/GO‐CI composites. Compared with SR/GO/CI, the SR/GO‐CI exhibited better thermal conduction and mechanical recovery properties. Moreover, the γ‐ray radiation shielding ability of SR/GO‐CI is much higher than that of pristine SR/GO/CI. CI particles are coated by GO nanosheets to increase surface area to prevent sedimentation of CI. It implies that SR‐GO/CI composite would have potential application as the radiation hardening material with thermal conductive and nuclear radiation shielding function.

Funder

Beijing Nova Program

National Natural Science Foundation of China

Publisher

Wiley

Subject

Materials Chemistry,Polymers and Plastics,Surfaces, Coatings and Films,General Chemistry

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