[2+4] Cycloaddition Product of an Amidinate Substituted Dialumene with Toluene-Reference-Cited by-同舟云学术

[2+4] Cycloaddition Product of an Amidinate Substituted Dialumene with Toluene

Published:2023-06-06 Issue:41 Volume:29 Page:
ISSN:0947-6539
Container-title:Chemistry – A European Journal
language:en
Short-container-title:Chemistry A European J

Author:

Kumar Arun¹,Yadav Komal²^ORCID,Graw Nico¹^ORCID,Pandey Madhusudan K.¹^ORCID,Herbst‐Irmer Regine¹^ORCID,Lourderaj Upakarasamy²,Stalke Dietmar¹^ORCID,Roesky Herbert W.¹^ORCID

Affiliation:

1. Institut für Anorganische Chemie Georg-August-Universität Göttingen 37077 Göttingen Germany

2. School of Chemical Sciences National Institute of Science Education and Research (NISER) Bhubaneswar An OCC of Homi Bhabha National Institute P. O. Jatni, Khurda Odisha India

Abstract

AbstractReduction of LAlI2(L=PhC(NiPr2C6H3)2) with two equivalents of KC8in toluene affords the [2+4]cycloaddition product of a dialumene with toluene. The mechanism for the formation of product complex was investigated using density functional theory (DFT) methods.

Publisher

Wiley

Subject

General Chemistry,Catalysis,Organic Chemistry

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