Induced CPL‐Active Materials Based on Chiral Supramolecular Co‐Assemblies

Author:

Zhang Yuxia12,Yu Wenting1,Li Hang1,Zheng Wenhua1,Cheng Yixiang1ORCID

Affiliation:

1. Nanjing University State Key Laboratory of Coordination Chemistry Jiangsu Key Laboratory of Advanced Organic Materials School of Chemistry and Chemical Engineering Nanjing 210023 P. R. China

2. Nanjing University of Posts and Telecommunications Key Laboratory for Organic Electronics & Information Displays (KLOEID) and Institute of Advanced Materials National Synergistic Innovation Center for Advanced Materials (SICAM) Nanjing 210023 P. R. China

Abstract

AbstractCircularly polarized luminescence (CPL) has attracted much interest due to its potential applications on chiral photonic techniques and optoelectronic materials science. As known, dissymmetry factor (gem) of CPL is one essential factor for evaluating the features of CPL‐active materials. Much attention has focused on how to increase thegemvalue, which is one of the most important issues for CPL practical applications. Recently, more and more works have demonstrated that chiral supramolecular could provide the significant strategy to improve thegemvalue through the orderly helical superstructure of chiral building blocks. Normally, this kind of chiral supramolecular assembly process can be accompanied by chirality transfer and induction mechanism, which can promote the amplification effect on the induced CPL of achiral dyes. In this review, we fully summarized recent advances on the induced CPL‐active materials of chiral supramolecular co‐assemblies, their applications in circularly polarized organic light‐emitting diodes (CP‐OLEDs) and current challenges.

Funder

National Natural Science Foundation of China

Publisher

Wiley

Subject

General Chemistry,Catalysis,Organic Chemistry

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