Highly Efficient Oxindole‐Based Molecular Photoswitches

Author:

Doellerer Daniel1ORCID,Pooler Daisy R. S.1ORCID,Guinart Ainoa1ORCID,Crespi Stefano12ORCID,Feringa Ben L.1ORCID

Affiliation:

1. Stratingh Institute for Chemistry University of Groningen, Nijenborgh 4 9747 AG Groningen The Netherlands

2. Department of Chemistry – Ångström Laboratory Uppsala University Box 523 751 20 Uppsala Sweden

Abstract

Abstract3‐Benzylidene‐indoline‐2‐ones play a prominent role in the pharmaceutical industry due to the diverse biomedical applications of oxindole heterocycles. Despite the extensive reports on their biological properties, these compounds have hardly been studied for their photochemical activity. Here, we present 3‐benzylidene‐indoline‐2‐ones as a promising class of photoswitches with high yields, robust photochemical switching with quantum yields reaching up to 50 % and potential for biological applications.

Funder

European Research Council

H2020 Marie Skłodowska-Curie Actions

Ministerie van Onderwijs, Cultuur en Wetenschap

Zernike Institute for Advanced Materials, Rijksuniversiteit Groningen

Publisher

Wiley

Subject

General Chemistry,Catalysis,Organic Chemistry

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