Ambiguous Faces of Water‐Based Inclusion Compounds: L4(4)8(8) Intercalato‐Clathrate Hydrate of Pt(II) Complex

Author:

Pietrzak Anna1ORCID,Wojciechowski Jakub2ORCID,Nowak Przemysław34ORCID,Gacki Michał1ORCID,Ochocki Justyn5ORCID,Wolf Wojciech M.1ORCID

Affiliation:

1. Institute of General and Ecological Chemistry Faculty of Chemistry Łódź University of Technology Żeromskiego 116 90-924 Łódź Poland

2. Rigaku Europe SE Hugenottenallee 167 Neu-Isenburg 63263 Germany

3. Centre of Molecular and Macromolecular Studies Polish Academy of Sciences Sienkiewicza 112 90-363 Łódź Poland

4. Bio-Med-Chem Doctoral School of University of Lodz and Lodz Institutes of the Polish Academy of Sciences University of Łódź Matejki 21/23 90-237 Łódź Poland

5. Department of Bioinorganic Chemistry Medical University of Łódź Muszyńskiego 1 90-151 Łódź Poland

Abstract

AbstractClathrate hydrates are among the most intensively studied H‐bond inclusion compounds. Despite the broad definition for this class of compounds, their meaning commonly refers to closed polyhedral nanocages that encapsulate small guest molecules. On the other hand, larger solutes enforce another type of encapsulation because of the solute size effect. Herein, we report a series of structures containing various molecules encapsulated by intercalated water layers constructed of polycyclic moieties of L4(4)8(8) topology. We parametrized the corrugation of individual layers and characterized interactions governing their formation. We suggested that these could be categorized as two‐dimensional clathrates based on the character of intra‐layer interactions and the effects observed between entrapped molecules and water‐based intercalators.

Publisher

Wiley

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3