Affiliation:
1. Wuhan Institute of Marine Electric Propulsion Wuhan 430064 China
2. Wuhan National Laboratory for Optoelectronics Huazhong University of Science and Technology Wuhan 430074 China
Abstract
AbstractTiNb2O7 with Wadsley–Roth phase delivers double theoretical specific capacity and similar working potential in comparison to spinel Li4Ti5O12, the commercial high‐rate anode material, and thus can enable much higher energy density of lithium‐ion batteries. However, the inter‐particle resistance within the high‐mass‐loading TiNb2O7 electrode would impede the capacity release for practical application, especially under fast‐charging conditions. Herein, 10–20 μm‐size carbon‐coated TiNb2O7 secondary particle (SP‐TiNb2O7) consisting of initial micro‐scale TiNb2O7 particles (MP‐TiNb2O7) was fabricated. The high crystallinity of active material could enable fast‐charge diffusion and electrochemical reaction rate within particles, and the small number of stacking layers of SP‐TiNb2O7 could reduce the large inter‐particle resistance that regular particle electrode often possess and achieve high compaction density of electrodes with high mass loading. The investigation on materials structure and electrochemical reaction kinetics verified the advances of the as‐fabricated SP‐TiNb2O7 in achieving superior electrochemical performance. The SP‐TiNb2O7 exhibited high reversible capacity of 292.7 mAh g−1 in the potential range of 1–3 V (Li+/Li) at 0.1 C, delivering high‐capacity release of 94.3 %, and high capacity retention of 86 % at 0.5 C for 250 cycles in half cell configuration. Particularly, the advances of such an anode were verified in practical 5 Ah‐level laminated full pouch cell. The as‐assembled LiFePO4||TiNb2O7 full cell exhibited a high capacity of 5.08 Ah at high charging rate of 6 C (77.9 % of that at 0.2 C of 6.52 Ah), as well as an ultralow capacity decay rate of 0.0352 % for 250 cycles at 1 C, suggesting the great potential for practical fast‐charging lithium‐ion batteries.
Subject
General Chemistry,Catalysis,Organic Chemistry