Hollow UiO‐66‐NH2 Encapsulated Pd Catalysts for Highly Selective Hydrogenation of Furfural to Furfuryl Alcohol

Author:

Zhao Bo1,Yao Yao2,Huang Kexin2,Li Jiaxin2,Chen Minjie2,Liu Chao2,Xu Hongjian2,Zhao Xinyu2,Chang Ganggang2ORCID

Affiliation:

1. School of Power Engineering Naval University of Engineering Wuhan 430033 China

2. School of Chemistry, Chemical Engineering and Life Science State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan 430070 China

Abstract

AbstractThe selective hydrogenation of furfural (FFA) to furfuryl alcohol (FA) is regarded as attractive transformation to achieve the sustainable synthesis of value‐added chemicals from biomass resources. However, the conventional supported catalysts are significantly restricted by their narrow pore size, ununiform dispersion and easy leaching or aggregation of catalytic sites. Herein, we designed hollow UiO‐66‐NH2 as the support to encapsulate Pd nanoparticles (Pd@H‐UiO‐66‐NH2) to achieve the highly active and selective conversion of FFA to FA. Benefiting from the void‐confinement effect and substrate enrichment of hollow structure, as well as the surface wrinkles, the as‐prepared catalyst Pd@H‐UiO‐66‐NH2 exhibited 96.8 % conversion of FFA with satisfactory selectivity reaching up to 92.4 % at 80 °C, 0.5 MPa H2 in isopropanol solvent within 6 h. More importantly, as‐prepared Pd@H‐UiO‐66‐NH2 catalyst exhibited excellent long‐term stability, as well as good universality toward a series of hydrogenation of unsaturated hydrocarbons.

Publisher

Wiley

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3