Affiliation:
1. Key Laboratory of Applied Surface and Colloid Chemistry Ministry of Education and School of Chemistry and Chemical Engineering Shaanxi Normal University Xi'an 710062 China
2. Department of Chemistry University of Liverpool Liverpool L69 7ZD UK
Abstract
AbstractThis paper reports a photochemical C−N coupling of abundant, but less reactive aryl chlorides, with structurally diverse primary and secondary amides by Ni‐mediated without an external photocatalyst. Under the irradiation of light (390–395 nm) with a soluble organic amine as the base, the reaction allows for the successful transformation of (hetero)aryl chlorides to a wide range of N‐aryl amides. More than 60 examples are shown, demonstrating the feasibility and applicability of this protocol in organic synthesis. Mechanic studies indicate that this amidation proceeds via a Ni(I)‐Ni(III) catalytic cycle.
Funder
National Natural Science Foundation of China
Subject
General Chemistry,Catalysis,Organic Chemistry
Cited by
16 articles.
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