Affiliation:
1. College of Polymer Science and Engineering Qingdao University of Science and Technology Zhengzhou Road 266042 Qingdao China
2. College of Chemical Engineering Qingdao University of Science and Technology Zhengzhou Road 266042 Qingdao China) Please change the image of the Frontispiece from the current image to the TOC image.
Abstract
AbstractHydrogen‐bonded organic frameworks (HOFs) are porous crystalline materials. The pores in HOFs are usually non‐covalent extrinsic pores constructed through the formation of the framework. Supramolecular macrocycles with intrinsic pores in their structures are good candidates for constructing HOFs with intrinsic pores from the macrocycles themselves, thus leading to hierarchically porous structures. Combining the macrocycle and HOFs will endow these hierarchically porous materials with enhanced properties and special functionalities. This review summarizes recent advances in macrocycle‐based HOFs, including the macrocycles used for constructing HOFs, the hierarchically porous structures of the HOFs, and the applications induced by the hierarchically HOFs porous structures. This review provides insights for future research on macrocycle‐based hierarchically porous HOFs and the appropriate applications of the unique structures.
Funder
National Natural Science Foundation of China
Natural Science Foundation of Shandong Province
Subject
General Chemistry,Catalysis,Organic Chemistry