Comment on “Persistent Room‐Temperature Radicals from Anionic Naphthalimides: Spin Pairing and Supramolecular Chemistry” and on “Persistent Radical Pairs between N‐Substituted Naphthalimide and Carbanion Exhibit p K a‐Dependent UV/Vis Absorption”

Author:

Korth Hans‐Gert1ORCID

Affiliation:

1. Institut für Organische Chemie Universität Duisburg-Essen Universitätsstr. 7 45117 Essen Germany

Publisher

Wiley

Subject

General Chemistry,Catalysis,Organic Chemistry

Reference22 articles.

1. Persistent Room‐Temperature Radicals from Anionic Naphthalimides: Spin Pairing and Supramolecular Chemistry

2. Online edition:https://materials.springer.com/bookshelf.

3. From the computedg-factor (2.0032) and the experimental center field of the EPR spectrum of the (clearly identified)N-alkyl naphthalimide radical anion (Figure 2 an experimental microwave frequency of 9103.9 MHz can be estimated. This in turn provides ag-factor of 2.0051 for the EPR spectrum of Figure 2 b (ref. [4]) in agreement with a nitroxide radical.

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