Oxygen‐Promoted on‐Surface Synthesis of Polyboroxine Molecules-Reference-Cited by-同舟云学术

Oxygen‐Promoted on‐Surface Synthesis of Polyboroxine Molecules

Published:2024-07-30 Issue:47 Volume:30 Page:
ISSN:0947-6539
Container-title:Chemistry – A European Journal
language:en
Short-container-title:Chemistry A European J

Author:

Toffoli Daniele¹²^ORCID,Turco Elia³^ORCID,Stredansky Matus²^ORCID,Costantini Roberto²³^ORCID,Dell'Angela Martina²^ORCID,Floreano Luca²^ORCID,Goldoni Andrea⁴^ORCID,Morgante Alberto²³^ORCID,Kladnik Gregor²⁵^ORCID,Cvetko Dean²⁵⁶^ORCID,de Oteyza Dimas G.⁷⁸^ORCID,Colazzo Luciano⁷⁹^ORCID,Mohammed Mohammed S. G.⁷⁹^ORCID,Sala Alessandro²³^ORCID,Comelli Giovanni²³^ORCID,Africh Cristina²^ORCID,Fronzoni Giovanna¹^ORCID,Balducci Gabriele¹^ORCID,Stener Mauro¹²^ORCID,Ustunel Hande¹⁰^ORCID,Cossaro Albano¹²^ORCID

Affiliation:

1. Department of Chemical and Pharmaceutical Sciences University of Trieste via L. Giorgieri 1 34127 Trieste Italy

2. CNR - Istituto Officina dei Materiali (IOM) Strada Statale 14 – km 163.5 34149 Trieste Italy

3. Department of Physics University of Trieste via A. Valerio 2 34127 Trieste Italy

4. Elettra-Sincrotrone Trieste S.C.p.A. Strada Statale 14 – km 163.5 34149 Trieste Italy

5. Faculty of Mathematics and Physics University of Ljubljana Jadranska 19 SI-1000 Ljubljana Slovenia

6. Jožef Stefan Institute Jamova 39 SI-1000 Ljubljana Slovenia

7. Donostia International Physics Center Paseo Manuel Lardizabal 4 E-20018 Donostia-San Sebastián Spain

8. Nanomaterials and Nanotechnology Research Center (CINN), CSOC-UNIOVI-PA 33940 El Entrego Spain

9. Centro de Física de Materiales (CSIC-UPV/EHU) – MPC Paseo Manuel de Lardizabal, 5 E-20018 Donostia-San Sebastián Spain

10. Department of Physics Middle East Technical University 06800 Ankara Turkey

Abstract

AbstractWe present a protocol for the on‐surface synthesis of polyboroxine molecules derived from boroxine molecules precursors. This process is promoted by oxygen species present on the Au(111) surface: oxygen atoms facilitate the detachment of naphthalene units of trinaphthyl‐boroxine molecules and bridge two unsaturated boroxine centers to form a boroxine‐O‐boroxine chemical motif. X‐ray spectroscopic characterization shows that, as the synthesis process proceeds, it progressively tunes the electronic properties of the interface, thus providing a promising route to control the electron level alignment.

Funder

HORIZON EUROPE Reforming and enhancing the European Research and Innovation system

Publisher

Wiley

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