A Silicon‐Stereogenic Silanol ‐ 18 O‐Isotope Labeling and Stereogenic Probe Reveals Hidden Stereospecific Water Exchange Reaction
Author:
Affiliation:
1. Inorganic Chemistry TU Dortmund University Otto-Hahn-Straße 6/6a 44227 Dortmund Germany
2. Center for Mass Spectrometry (CMS) TU Dortmund University Otto-Hahn-Straße 6/6a 44227 Dortmund Germany
Funder
Verband der Chemischen Industrie
Deutsche Forschungsgemeinschaft
Publisher
Wiley
Subject
General Chemistry,Catalysis,Organic Chemistry
Link
https://onlinelibrary.wiley.com/doi/pdf/10.1002/chem.202202935
Reference61 articles.
1. Design and Implementation of New, Silicon-Based, Cross-Coupling Reactions: Importance of Silicon−Oxygen Bonds
2. A novel CC bond forming reaction of aryl-and alkenylsilanols. A halogen-free Mizoroki-Heck type reaction
3. Hydroxorhodium Complex-Catalyzed Carbon−Carbon Bond-Forming Reactions of Silanediols with α,β-Unsaturated Carbonyl Compounds. Mizoroki-Heck-Type Reaction vs Conjugate Addition
4. Silicon and Oxygen’s Bond of Affection: An Acyclic Three-Coordinate Silanone and Its Transformation to an Iminosiloxysilylene
5. A Silylene–Borane Lewis Pair as a Tool for Trapping a Water Molecule: Silanol Formation and Dehydrogenation
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