Spin in Organic Cocrystals

Author:

Zhang Cheng12ORCID,Wang Xin2,Li Yang1ORCID,Sun Yanqiu3,Zhang Qichun2ORCID

Affiliation:

1. Jiangsu Key Laboratory of Micro and Nano Heat Fluid Flow Technology and Energy Application Institution School of Physical Science and Technology Suzhou University of Science and Technology Suzhou Jiangsu 215009 China

2. Department of Materials Science and Engineering Department of Chemistry & Center of Super-Diamond and Advanced Films (COSDAF) City University of Hong Kong Hong Kong SAR 999077 China

3. School of Chemistry and Life Sciences Suzhou University of Science and Technology Suzhou Jiangsu 215009 China

Abstract

AbstractOrganic spintronics has caused a huge revolution in creating highly efficient low‐power circuits. Spin manipulation in organic cocrystals has become a promising strategy to uncover more chemicophysical properties for diverse applications. In this Minireview, we summarize the recent advancements of spin properties in organic charge‐transfer cocrystals, and briefly describe the possible mechanisms behind them. Beside the known spin properties (spin multiplicity, mechanoresponsive spin, chiral orbit and spin‐crossover) in binary/ternary cocrystals, other spin phenomena in radical cocrystals and spin transport are also summarized and discussed. Hopefully, deep understanding of current achievements, challenges and perspectives will offer the clear direction for the introduction of spin in organic cocrystals.

Funder

City University of Hong Kong

National Natural Science Foundation of China

Six Talent Peaks Project in Jiangsu Province

Jiangsu Key Laboratory for Chemistry of Low-Dimensional Materials

Publisher

Wiley

Subject

General Chemistry,Catalysis,Organic Chemistry

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