Gd3TeBO9: A Rare‐Earth Borate with Significant Magnetocaloric Effect

Author:

Zhou Changqing12ORCID,Li Rukang12ORCID

Affiliation:

1. Beijing Center for Crystal Research and Development Key Laboratory of Functional Crystals and Laser Technology Technical Institute of Physics and Chemistry Chinese Academy of Sciences Beijing 100190 China

2. Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences Beijing 100049 China

Abstract

AbstractMagnetic refrigeration technology based on Gd‐based paramagnets is expected to be applied to refrigeration in extremely low temperatures, thereby reducing the consumption of liquid helium. Here, we obtained a compound, Gd3TeBO9 with high Gd3+ concentration through element substitution. The Gd3+ concentration in this compound is as high as 2.4×1024 ions/kg, which is 33 % higher than the commercial Gd3Ga5O12 (GGG), and further magnetic tests show that Gd3TeBO9 has a large magnetic entropy change (57.44 J/(kg K) and 408 mJ/(cm3 K) at 2.6 K and 7 T), which is 1.5 times that of GGG, implying the possibility of its further development as an potential magnetocaloric material.

Funder

National Natural Science Foundation of China

Publisher

Wiley

Subject

General Chemistry,Catalysis,Organic Chemistry

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