One‐pot Synthesis of PdCuAg and CeO2 Nanowires Hybrid with Abundant Heterojunction Interface for Ethylene Glycol Electrooxidation

Author:

Fan Dongping12,Zheng Jinyu1,Xiang Xin1,Xu Dongdong13ORCID

Affiliation:

1. Jiangsu Key Laboratory of New Power Batteries, Jiangsu Collaborative Innovation Center of Biomedical Functional Materials, School of Chemistry and Materials Science Nanjing Normal University Nanjing, Jiangsu 210023 China

2. College of Chemistry Sichuan University Chengdu, Sichuan 610064 China

3. State Key Laboratory of Coordination Chemistry Nanjing University Nanjing 210023 P. R. China

Abstract

AbstractIntroducing CeO2 into Pd‐based nanocatalysts for electrocatalytic reactions is a good way to solve the intermediate toxicity problem and improve the catalytic performance. Here we reported a simple strategy to synthesize the PdCuAg and CeO2 nanowires hybrid via a one‐pot synthesis process under strong nanoconfined effect of specific surfactant as templates. Owing to the structural (ultrathin nanowires, abundant heterojunction/interfaces between metal and metal oxide) and compositional (Pd, Cu, Ag, CeO2) advantages, the hybrid showed significantly enhanced catalytic activity (6.06 A mgPd−1) and stability, accelerated reaction rate, and reduced activation energy toward electrocatalytic ethylene glycol oxidation reaction.

Publisher

Wiley

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