Affiliation:
1. Anhui Province Key Laboratory of Structure and Functional Regulation of Hybrid Materials College of Chemistry & Chemical Engineering Department of Chemistry Anhui University 230601 Hefei Anhui P. R. China
2. Key Laboratory of Structure and Functional Regulation of Hybrid Materials Anhui University Ministry of Education 230601 Hefei P. R. China
Abstract
AbstractA three‐component umpolung cascade coupling reaction of phenols, C60, and different nucleophiles which includes H2O, alcohols, triphenylamines and carbazoles was developed. Furthermore, one‐pot 1,4‐bisphenol coupling on C60 has been realized by this method. This practical protocol features high chemo‐ and regioselectivity, wide substrate range, easy operation and low cost, thus providing a robust method for the one‐pot synthesis of various unsymmetrical 1,4‐[60]fullerephenols.
Funder
National Natural Science Foundation of China
Subject
General Chemistry,Catalysis,Organic Chemistry