Rh(I)‐Catalyzed [4+3]/[4+1] Cycloaddition of Diene‐Vinylcyclopropanes and Carbon Monoxide to Access Angular 5/7/5 Tricycles-Reference-Cited by-同舟云学术

Rh(I)‐Catalyzed [4+3]/[4+1] Cycloaddition of Diene‐Vinylcyclopropanes and Carbon Monoxide to Access Angular 5/7/5 Tricycles

Published:2023-12-04 Issue:5 Volume:30 Page:
ISSN:0947-6539
Container-title:Chemistry – A European Journal
language:en
Short-container-title:Chemistry A European J

Author:

Yang Jun¹,Zhang Pan¹,Shen Zeyuan¹,Yu Zhi‐Xiang¹^ORCID

Affiliation:

1. Beijing National Laboratory for Molecular Sciences (BNLMS) Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education College of Chemistry Peking University Beijing 100871 China

Abstract

AbstractReport here is a Rh‐catalyzed [4+3]/[4+1] cycloaddition of diene‐vinylcyclopropanes (diene‐VCPs) and carbon monoxide to access compounds with angular 5/7/5 tricyclic skeleton found in natural products. The reaction has broad scope and further transformation of the [4+3]/[4+1] cycloadduct was also investigated. How this [4+3]/[4+1] reaction occurs and why its competing [4+3] reaction is disfavored have been investigated computationally.

Funder

National Natural Science Foundation of China

Publisher

Wiley

Subject

General Chemistry,Catalysis,Organic Chemistry

Reference43 articles.

2. Fenestranes in Synthesis: Unique and Highly Inspiring Scaffolds

3. An overview of the recent synthetic studies toward penifulvins and other fenestranes

4. Intricarene, an Unprecedented Trispiropentacyclic Diterpene from the Caribbean Sea Plume Pseudopterogorgia kallos

5. The structure of laurenene, a new diterpene from the essential oil of Dacrydium cupressinum. Part 1

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