Affiliation:
1. College of Chemistry and Materials Science Fujian Normal University Fuzhou 350002 P. R. China
2. State Key Laboratory of Structural Chemistry Center for Excellence in Molecular Synthesis Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou 350002 China
Abstract
AbstractCarboxylic acids are abundant, low cost and environmentally friendly, direct convert carboxylic acids into valued‐added compounds are in high demand. Herein, we report a Rh(I) catalyzed direct decarbonylative borylation of aryl and alkyl carboxylic acid using TFFH as activator. This protocol features excellent functional‐group tolerance and a broad substrate scope including natural product and drugs. A gram‐scale decarbonylative borylation reaction of Probenecid is also presented. In addition, the utility of this strategy is highlighted by a one‐pot decarbonylative borylation/ derivatization sequence.
Funder
National Key Research and Development Program of China
National Natural Science Foundation of China
Subject
General Chemistry,Catalysis,Organic Chemistry
Cited by
1 articles.
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