Affiliation:
1. School of Chemistry and Chemical Engineering Yangzhou University Yangzhou 225002 P. R. China
2. School of Chemical Engineering, College of Engineering Sungkyunkwan University 2066, Seobu-ro, Jangan-gu, Suwon-si Gyeonggi-do 440-746 Republic of Korea
Abstract
AbstractDoping Co atoms into Ru lattices can tune the electronic structure of active sites, and the conductive MXene can adjust the electrical conductivity of catalysts, which are both favorable for improving the electrocatalytic activity of the catalyst for water splitting. Here, ruthenium‐cobalt bimetallic nanoalloys coupled with exfoliated Ti3C2Tx MXene (RuCo−Ti3C2Tx) have been constructed by ice‐templated and thermal activation. Due to the strong interaction between the RuCo nanoalloys and conductive MXene, RuCo−Ti3C2Tx not only exhibits an excellent hydrogen evolution reaction (HER) performance with a low overpotential and Tafel slope (60 mV, 34.8 mV dec−1 in 0.5 M H2SO4 and 52 mV, 38.7 mV dec−1 in 1 M KOH), but also good oxygen evolution reaction (OER) performance in an alkaline electrolyte (266 mV, 111.1 mV dec−1 in 1 M KOH). The assembled RuCo−Ti3C2Tx||RuCo−Ti3C2Tx electrolyzer requires a lower potential (1.56 V) than does the Pt/C||RuO2 electrolyzer at 10 mA cm−2. A boosted catalytic HER activity from immobilizing the RuCo nanoalloys on MXene was unveiled by density functional theory calculations. This study provides a feasible and efficient strategy for developing MXene‐based catalysts for overall water splitting.
Funder
National Natural Science Foundation of China
Six Talent Peaks Project in Jiangsu Province
Subject
General Chemistry,Catalysis,Organic Chemistry