Affiliation:
1. Department of Chemistry School of Science Kwansei Gakuin University Gakuen Uegahara 1 Sanda Hyogo 669-1330 Japan
2. JST-PRESTO 7 Gobancho, Chiyoda Tokyo 102-0076 Japan
Abstract
AbstractThe discovery of new catalytic applications for metals remains an important goal in organic synthesis. If a catalyst has multiple functions, such as inducing bond cleavage and formation, it can streamline multi‐step transformations. Herein, the Cu‐catalyzed synthesis of imidazolidine through heterocyclic recombination between aziridine and diazetidine is reported. Mechanistically, Cu catalyzes the conversion of diazetidine into the corresponding imine, which then reacts with aziridine to form imidazolidine. The scope is sufficiently wide to form various imidazolidines, as many functional groups are compatible with the reaction conditions.
Funder
Precursory Research for Embryonic Science and Technology
Subject
General Chemistry,Catalysis,Organic Chemistry
Cited by
2 articles.
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