A Metallabicycle From Thiocarbonyl‐Cyclopropenium Coupling-Reference-Cited by-同舟云学术

A Metallabicycle From Thiocarbonyl‐Cyclopropenium Coupling

Published:2023-08-02 Issue:49 Volume:29 Page:
ISSN:0947-6539
Container-title:Chemistry – A European Journal
language:en
Short-container-title:Chemistry A European J

Author:

Watson Lachlan J.¹^ORCID,Hill Anthony F.¹^ORCID

Affiliation:

1. Research School of Chemistry Australian National University Sullivans Creek Road Canberra, ACT Australia

Abstract

AbstractAddition of triphenylcyclopropenium bromide to the thiocarbonyl complex [RhCl(CS)(PPh3)2] affords novel bicyclic metalla‐3‐mercapto‐thiapyrylliums [Rh(κ2‐C,S‐C5S2Ph3)(PPh3)2X2] (X=Cl, Br) – heterocycles with no metal‐free isolobal precedent. Halide abstraction with silver triflate (AgOTf) in acetonitrile affords the salt [Rh(κ2‐C,S‐C5S2Ph3)(NCMe)2(PPh3)2{Ag(OH2)2}{Ag(OTf)3}]‐OTf which in turn reacts with sodium chloride to return [Rh(κ2‐C,S‐C5S2Ph3)(PPh3)2Cl2].

Funder

Australian Research Council

Publisher

Wiley

Subject

General Chemistry,Catalysis,Organic Chemistry

Link

https://chemistry-europe.onlinelibrary.wiley.com/doi/pdf/10.1002/chem.202301753

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