Affiliation:
1. Chair of Hydrogeology, TUM School of Engineering and Design Technical University of Munich Munich Germany
2. Institute of Bio‐ and Geoscience (IBG‐3, Agrosphere) Forschungszentrum Jülich GmbH Jülich Germany
3. Research Area 1 “Landscape Functioning”, Working Group “Hydropedology” Leibniz Centre for Agricultural Landscape Research (ZALF) Müncheberg Germany
4. Institute of Crop Science and Resource Conservation – Soil Science and Soil Ecology University of Bonn Bonn Germany
5. Faculty of Chemistry and Water Chemistry Technical University of Munich Munich Germany
Abstract
AbstractThis study investigates the contamination potential of herbicides to groundwater with the help of numerical modeling (HYDRUS‐1D) and stable carbon isotopes for characterizing biodegradation. Four herbicides, metolachlor, terbuthylazine, prosulfuron, and nicosulfuron, were applied over a period of 4.5 years on two lysimeters located in Wielenbach, Germany, and monitored by lysimeter drainage. These lysimeters contained soil cores dominated by sandy gravel (Ly1) and clayey sandy silt (Ly2) and were both cropped with maize (Zea mays). In the preceding study, we characterized flow within the lysimeters by using stable water isotopes and unsaturated flow models. Building up on these findings, models were extended for describing reactive transport of the herbicides and investigating process contributions. At the end of the experiment, 0.9%–15.9% of the applied herbicides (up to 20.9% if including metabolites) were recovered by lysimeter drainage. Metabolite formation and accumulation was observed, and biodegradation was also indicated by small changes in carbon isotope signals (δ13C) between applied and leached herbicides. Model setups could describe the dynamics of herbicide concentrations in lysimeter drainage well. Concentration peaks in drainage were partly also linked with strong precipitation events, indicating preferential flow influence. The soil core with the coarser texture (Ly1) showed less herbicide leaching than the finer texture (Ly2), which can be explained by a larger mobile phase in Ly1. Overall, our approaches and findings contribute to the understanding of multi‐process herbicide transport in the vadose zone and leaching potentials to groundwater, where δ13C can provide valuable hints for microbial degradation.
Cited by
1 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献