Waterborne polyurethane dispersions based on polypropylene glycol/polycarbonate diol: Evaluation of their use as wood protective coatings

Abstract

AbstractWhen exposed to the open air, the wood can change its physical and structural properties due to the combined effect of ultraviolet radiation, oxygen, humidity, atmospheric pollutants, and microorganisms. The demand for durable coatings with application to wooden structures or pieces is always a relevant topic. Waterborne polyurethane (WPU) dispersions as wood protective coatings might be attractive, especially outdoors. In this work, WPU dispersions have been synthesized from isophorone diisocyanate and different ratios of polypropylene glycol and polycarbonate (PC) diol. Synthesized polyurethanes were applied to wood surfaces as a coating. The results showed that the partial and total replacement of polypropylene glycol (PPG) by PC influences the mechanical, thermal, and structural properties of the films obtained from aqueous polyurethane dispersions. In addition, a simple and promising methodology based on Fourier‐transform infrared (FTIR) spectra was proposed to determine the polycarbonate content in poly(carbonate‐ether‐urethane). The synthesized coatings reduced water absorption by the wood, especially the one with a 25:75 polycarbonate to PPG ratio. The applied coating does not impact the final color of the wood, allowing a natural aging effect. Polyurethanes are promising for use as coatings for wood.