Al2O3‐Stabilized Pt Nanozymes: Peroxidase Mimetics and Application in Glucose Detection

Author:

Ma Yawen1,Yi Siwen1,Gao Chuhan2,Yang Man3,Feng Dan4,Ren Yujing1,Ge Huibin1ORCID

Affiliation:

1. Interdisciplinary Research Center of Biology & Catalysis School of Life Sciences Northwestern Polytechnical University 710072 Xi'an P. R. China

2. School of Chemistry and Chemical Engineering Northwestern Polytechnical University 710072 Xi'an P. R. China

3. School of Materials Science and Engineering Xi'an University of Technology 710048 Xi'an P. R. China

4. Analytical & Testing Center Northwestern Polytechnical University 710072 Xi'an P. R. China

Abstract

AbstractAs promising alternatives for natural enzymes, much attention has been paid to nanozymes. And our recent study showed that the medium acid sites on the support are the active sites for the adsorption and oxidation of the substrate. Thus, in this work, due to the abundance of medium acid sites, Al2O3 was chosen as the support to prepare Pt/Al2O3 nanozymes. Through the Pt/Al2O3 samples, we further proved that the distribution of the Pt clusters and the amount of the medium acid sites can significantly influence the peroxidase‐like activity. Then the Pt/Al2O3 sample was used for the detection of glucose. And as low as 0.96 μM glucose could be detected with a linear range from 5–60 μM via our method. This work showed the great potential applications of the easily prepared Pt/Al2O3 samples in varieties of simple, robust, and easy‐to‐make analytical approaches in the future.

Funder

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

Publisher

Wiley

Subject

General Chemistry

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