Insight into the Structure of MOF‐Containing Hybrid Polymeric Microspheres

Author:

Goliszek Marta1,Kochaniec Maria2,Podkościelna B. Beata3ORCID

Affiliation:

1. Analytical Laboratory Institute of Chemical Science Faculty of Chemistry Maria Curie-Skłodowska University M. Curie-Skłodowska Sq. 3 20-031 Lublin Poland

2. Chemical Faculty Warsaw University of Technology Noakowskiego 3 00-664 Warsaw Poland

3. Department of Polymer Chemistry Institute of Chemical Science Faculty of Chemistry Maria Curie-Skłodowska University Gliniana 33 20-614 Lublin Poland

Abstract

AbstractPolymer science exploited metal organic frameworks (MOFs) for various purposes, which is due to the fact that these materials are ideal platforms for identifying design features for advanced functional materials. The mechanism of polymerization using MOFs, is still largely unexplored and the detailed characterization of both materials in essential to understand the important interactions between the components. In this work modern advanced research methods were used to investigate the properties of MOF‐containing hybrid polymeric microspheres. Hydrothermal conversion of CFA‐derived iron particles was used to obtain MOF nanostructures, which were then introduced to the structure of hybrid polymer microspheres based on ethylene glycol dimethylacrylate (EGDMA) and triethoxyvinylsilane (TEVS). Chemical structures were confirmed by ATR‐FTIR method. To provide information about the elemental composition of the tested materials and for the determination of chemical bonds present in the tested samples XPS method was applied. Morphology was studied using SEM microscopy, whereas porosity was investigated using ASAP technique. Swellability coefficients were determined using typical organic solvents and distilled water. Moreover, the ecological aspect concerning the use of fly ashes deserves to be emphasized.

Publisher

Wiley

Subject

Physical and Theoretical Chemistry,Atomic and Molecular Physics, and Optics

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