Increasing Complexity in Adamantyl Thioethers Characterized by Rotational Spectroscopy-Reference-Cited by-同舟云学术

Increasing Complexity in Adamantyl Thioethers Characterized by Rotational Spectroscopy

Published:2023-10-09 Issue:23 Volume:24 Page:
ISSN:1439-4235
Container-title:ChemPhysChem
language:en
Short-container-title:ChemPhysChem

Author:

Pinacho Pablo¹²^ORCID,Loru Donatella¹^ORCID,Šumanovac Tatjana³,Šekutor Marina³^ORCID,Schnell Melanie¹⁴^ORCID

Affiliation:

1. Deutsches Elektronen-Synchrotron DESY Notkestr. 85 22607 Hamburg Germany

2. Present address: Physical Chemistry Department University of the Basque Country (UPV/EHU) B° Sarriena, S/N 48940 Leioa Spain

3. Department of Organic Chemistry and Biochemistry Ruđer Bošković Institute Bijenička cesta 54 10000 Zagreb Croatia

4. Christian-Albrechts-Universität zu Kiel Institute of Physical Chemistry Max-Eyth-Str. 1 24118 Kiel Germany

Abstract

AbstractWe report on the synthesis and characterization using high‐resolution rotational spectroscopy of three bulky thioethers that feature an adamantyl group connected to a sulfur atom. Detailed experimental and theoretical structures are provided and compared with the 1,1′‐diadamantyl ether. In addition, we expand on previous findings concerning microsolvation of adamantyl derivatives by investigating the cluster formation between these thioethers and a water molecule. The investigation of such clusters provides valuable insights into the sulfur‐centered hydrogen bonding in thioethers with increasing size and steric repulsion.

Funder

Hrvatska Zaklada za Znanost

European Cooperation in Science and Technology

Publisher

Wiley

Subject

Physical and Theoretical Chemistry,Atomic and Molecular Physics, and Optics

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