Affiliation:
1. Department of Chemistry Scottish Church College 1 & 3, Urquhart Square Kolkata 700006 India
2. School of Chemical Science Indian Association for the Cultivation of Science Jadavpur Kolkata 700032 India
Abstract
AbstractThe effects of discontinuously time‐varying perturbations on the dynamics of a particle moving in harmonic, symmetric double well and symmetric triple well potentials, are investigated both classically and quantum mechanically. The quantum dynamics is followed using the time‐dependent Fourier grid Hamiltonian (TDFGH) method while the classical dynamics is analyzed within the framework of classical Hamiltonian mechanics. Depending on the spatial symmetry of the perturbation and the characteristic features of the reversal time
, different types of ‘phase space’ structures are observed in each of the potentials. For symmetric double and triple well potentials, quantum dynamics reveals that complete destruction of tunnelling (CDT) can be achieved in the presence of a time‐dependent spatially asymmetric perturbing field that is continuous in time. Any discontinuity in time‐variation of the perturbation may induce over the barrier transition. The relevance of these results in the context of (i) tunnelling control and (ii) quantum computing with 3‐state or 2‐state quantum registers is briefly discussed.
Subject
Physical and Theoretical Chemistry,Atomic and Molecular Physics, and Optics
Cited by
1 articles.
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