Affiliation:
1. Jiangsu Key Laboratory of Pesticide Science and Department of Chemistry College of Sciences Nanjing Agricultural University Nanjing 210095
Abstract
AbstractSulfonyl‐tethered N‐containing heterocycles are valuable building blocks in synthetic and pharmaceutical chemistry. Recently, the installation of fluoroalkanesulfonyl groups into heterocycles via the difunctionalization of alkenes still remains challenging. Herein in this work, an imino‐fluoroalkanesulfonylation of γ,δ‐unsaturated oxime esters has been achieved via photoredox/Cu dual catalysis. A variety of fluoroalkanesulfonyl‐tethered pyrroline derivatives have been readily synthesized in moderate to good yields under mild conditions.
Funder
Natural Science Foundation of Jiangsu Province
National Natural Science Foundation of China
Fundamental Research Funds for the Central Universities