Cobalt‐Catalyzed Diastereo‐ and Enantioselective Hydroarylation of Cyclopropenes with Arylboronic Acids-Reference-Cited by-同舟云学术

Cobalt‐Catalyzed Diastereo‐ and Enantioselective Hydroarylation of Cyclopropenes with Arylboronic Acids

Published:2023-01-31 Issue:3 Volume:12 Page:
ISSN:2193-5807
Container-title:Asian Journal of Organic Chemistry
language:en
Short-container-title:Asian J Org Chem

Author:

Zhang Jiwu¹²,Wang Lei²,Chong Qinglei²,Meng Fanke¹²³^ORCID

Affiliation:

1. College of Chemistry and Material Science Sichuan Normal University Chengdu Sichuan 610066 P. R. China

2. State Key Laboratory of Organometallic Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry University of Chinese Academy of Sciences 345 Lingling Road Shanghai 200032 P. R. China

3. School of Chemistry and Materials Science, Hangzhou Institute for Advanced Study University of Chinese Academy of Sciences Hangzhou 310024 P. R. China

Abstract

AbstractCatalytic diastereo‐ and enantioselective hydroarylation of 3,3‐disubstituted cyclopropenes with easily accessible arylboronic acids promoted by a chiral phosphine‐Co complex is presented. Such a process represents an unprecedented Co‐catalyzed approach for direct introduction of a variety of aryl groups onto the cyclopropane motif, affording multisubstituted cyclopropanes in up to 86% yield with greater than 95 : 5 dr and 99 : 1 er.

Funder

National Natural Science Foundation of China

Publisher

Wiley

Subject

Organic Chemistry

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/ajoc.202200720

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