Diastereoselective Rhodium‐Catalyzed [(3+2+2)] Carbocyclization Reactions with Tethered Alkynylidenecyclopropanes: Synthesis of the Tremulane Sesquiterpene Natural Products

Author:

Evans P. Andrew12ORCID,Dushnicky Molly J.1,Cho Dasol34,Majhi Jadab1,Choi Seulhui34,Pipaliya Bhavin V.1ORCID,Inglesby Phillip A.5,Baik Mu‐Hyun34

Affiliation:

1. Department of Chemistry Queen's University 90 Bader Lane Kingston Ontario K7L 3N6 Canada

2. Xiangya School of Pharmaceutical Science Central South University Changsha 410013 Hunan P. R. of China

3. Department of Chemistry Korea Advanced Institute of Science and Technology (KAIST) Daejeon 34141 Republic of Korea

4. Center for Catalytic Hydrocarbon Functionalizations Institute for Basic Science (IBS) Daejeon 34141 Republic of Korea

5. Department of Chemistry The University of Liverpool Crown Street Liverpool L69 7ZD UK

Funder

Government of Ontario

Natural Sciences and Engineering Research Council of Canada

Royal Society

Institute for Basic Science

Publisher

Wiley

Subject

Organic Chemistry

Reference72 articles.

1. For a recent review of cycloaddition and cycloisomerization reactions see:Comprehensive Organic Synthesis II Vol. 5(Eds.: P. Knochel G. A. Molander A. Fürstner) Elsevier: Waltham 2014.

2. For recent reviews on metal-catalyzed higher-order carbocyclization reactions see:

3. Stereoselective transition metal-catalysed higher-order carbocyclisation reactions

4. Development of transition-metal-catalyzed cycloaddition reactions leading to polycarbocyclic systems

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