Affiliation:
1. Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources International Innovation Center for Forest Chemicals and Materials Jiangsu Province Key Laboratory of Green Biomass-based Fuels and Chemicals College of Chemical Engineering Nanjing Forestry University Nanjing 210037 China
2. College of Life Sciences and Medicine Zhejiang Sci Tech University Hangzhou 310018 China
Abstract
AbstractPhotocatalytic generation of alkoxy radicals is fast emerging as an essential method for the generation of diverse and valuable radicals from inert C−H and C−C bonds for the construction of various C(sp3)−C(sp3), C(sp3)−C(sp2), C(sp3)−C(sp), and C−heteroatom bonds under mild condition. This review is a comprehensive evaluation of the studies using N‐alkoxyphthalimide (NAPI) derivatives as tunable oxygen radical precursors in photoredox catalysis, highlighting alkoxy radical enabled 1,2‐, 1,5‐hydrogen atom transfer, and β‐fragmentation (deformylation) process to generate versatile carbon‐centered radical intermediates with diverse reactivity profiles.
Funder
National Natural Science Foundation of China
Cited by
1 articles.
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