Affiliation:
1. Advanced Materials Laboratory, Department of Chemistry, School of Applied Sciences KIIT Deemed to be University Bhubaneswar India
Abstract
AbstractIn the present research, thermoplastic polyurethane/polypyrrole (TPU/PPy) dielectric composites film and the lightweight foamyfilm are fabricated using the most simplified solvent casting and modified phase separation water immersion techniques, respectively. The establishment of chemical interaction and morphological investigations of the fabricated systems are analyzed by Raman spectroscopy and field emission scanning electron microscope (FESEM), respectively. Various dielectric properties, together with complex impedance, are determined over a wide range of frequencies (1 Hz–1 MHz) and temperatures (25°C–120°C). Most interestingly, above 30 Hz frequency, a significantly low value (<0.1) dielectric loss tangent (tanδ) is obtained at ambient temperature. A 90:10 foamyfilm exhibits a dielectric permittivity (ε') and tanδof 236 and 0.05 at 50 Hz frequency, respectively. Both 90:10 film and foamyfilm systems exhibit a significantly increasing trend ofε′ as well as low tanδwith an increase in temperature over a wide range of frequencies. The thermogravimetric analysis (TGA) results of the 90:10 film and foamyfilm indicate the superior thermal stability of the 90:10 foamyfilm system. Based on the obtained low dielectric loss, the fabricated dielectric film, and foamyfilm can be employed in energy storage and high‐temperature sensing applications.
Subject
Materials Chemistry,Polymers and Plastics,Surfaces, Coatings and Films,General Chemistry
Cited by
1 articles.
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