Photo‐Induced C1 Substitution Using Methanol as a C1 Source

Author:

Li Hongmei1,Li Chao12,Liu Wei3,Yao Yanling4,Li Yuanhua4,Zhang Bing25,Qiu Chuntian23ORCID

Affiliation:

1. College of Mechanical Engineering College of Food and Bioengineering Chengdu University Chengdu 610106 P.R. China

2. ZJU-Hangzhou Global Scientific and Technological Innovation Center Zhejiang University Hangzhou 311215 P.R. China

3. International Collaborative Laboratory of 2D Materials for Optoelectronics Science and Technology of Ministry of Education Institute of Microscale Optoelectronics Shenzhen University Shenzhen 518060 P.R. China

4. School of Chemistry and Materials Engineering Huizhou University Huizhou 516007 P.R. China

5. State Key Laboratory of Chemical Engineering Institute of Pharmaceutical Engineering College of Chemical and Biological Engineering Zhejiang University Hangzhou 310027 P.R. China

Abstract

AbstractThe development of sustainable and efficient C1 substitution methods is of central interest for organic synthesis and pharmaceuticals production, the methylation motifs bound to a carbon, nitrogen, or oxygen atom widely exist in natural products and top‐selling drugs. In the past decades, a number of methods involving green and inexpensive methanol have already been disclosed to replace industrial hazardous and waste‐generating C1 source. Among the various efforts, photochemical strategy is considered as a “renewable” alternative that shows great potential to selectively activate methanol to achieve a series of C1 substitutions at mild conditions, typically C/N‐methylation, methoxylation, hydroxymethylation, and formylation. Herein the recent advances in selective transformation of methanol to various C1 functional groups via well‐designed photochemical systems involving different types of catalysts or not is systematically reviewed. Both the mechanism and corresponding photocatalytic system were discussed and classified on specific methanol activation models. Finally, the major challenges and perspectives are proposed.

Funder

National Natural Science Foundation of China

Basic and Applied Basic Research Foundation of Guangdong Province

National Postdoctoral Program for Innovative Talents

Publisher

Wiley

Subject

General Energy,General Materials Science,General Chemical Engineering,Environmental Chemistry

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