Transition‐Metal‐Free Unusual Oxidative Cleavage of Homoallylic Alcohol and Its Application in the Upcycling of Terpene to Value‐Added Chemicals-Reference-Cited by-同舟云学术

Transition‐Metal‐Free Unusual Oxidative Cleavage of Homoallylic Alcohol and Its Application in the Upcycling of Terpene to Value‐Added Chemicals

Published:2023-03-20 Issue:9 Volume:16 Page:
ISSN:1864-5631
Container-title:ChemSusChem
language:en
Short-container-title:ChemSusChem

Author:

Lee Tae Woo¹,Yang Hye Sung¹^ORCID,Dawange Monali¹,Han Young Kwang¹,Yang Jung Woon¹

Affiliation:

1. Department of Energy Science Sungkyunkwan University Suwon 16419 South Korea

Abstract

AbstractA NaOtBu−O2‐mediated oxidative dehomologation of homoallylic alcohols into structurally different carboxylic acids through direct oxidative cleavage of either the C(sp2)−C(sp2) or C(sp3)−C(sp3) bond utilizing enolate chemistry was demonstrated. Furthermore, under transition‐metal‐free conditions, this protocol has been applied to convert terpene as biomass feedstock into value‐added chemicals.

Funder

National Research Foundation

Korea Basic Science Institute

Publisher

Wiley

Subject

General Energy,General Materials Science,General Chemical Engineering,Environmental Chemistry

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/cssc.202202387

Reference51 articles.

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