Liquid Redoxmers for Nonaqueous Redox Flow Batteries

Author:

Robertson Lily A.12ORCID,Afsar Uddin Mohammad12345ORCID,Shkrob Ilya A.12ORCID,Moore Jeffrey S.134ORCID,Zhang Lu12ORCID

Affiliation:

1. Joint Center of Energy Storage Research (JCESR) Argonne National Laboratory Lemont Illinois 60439 United States

2. Chemical Sciences and Engineering Division Argonne National Laboratory Lemont Illinois 60439 United States

3. Department of Chemistry University of Illinois at Urbana-Champaign Urbana Illinois 61801 United States

4. Beckman Institute for Advanced Science and Technology University of Illinois at Urbana-Champaign Urbana Illinois 61801 United States

5. Instituto de Ciencia de Materiales de Madrid Madrid 20849 Spain

Abstract

AbstractRedoxmers are organic active molecules storing electrochemical energy in nonaqueous redox flow batteries (NRFBs). Increasing the solubility of redoxmers is an important approach for increasing energy density of NRFBs as effective redoxmer concentration determines how much electricity can be stored in a given volume. Molecular engineering redoxmers towards liquid forms is regarded as one promising strategy as liquid redoxmers represent an extreme scenario where fluidity is maintained at maximum concentration using a minimum amount of supporting solvents. In this Perspective, recent examples of liquid redoxmers as well as their development strategy will be discussed.

Publisher

Wiley

Subject

General Energy,General Materials Science,General Chemical Engineering,Environmental Chemistry

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