Affiliation:
1. College of Materials and Chemical Engineering Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion Materials China Three Gorges University Yichang 443002 P. R. China
2. Hubei Three Gorges Laboratory Yichang 443007 P. R. China
Abstract
AbstractLi3VO4 is a promising anode material for use in lithium‐ion batteries, however, the conventional synthesis methods for Li3VO4 anodes involve the separate use of lithium and carbon sources, resulting in inefficient contact and low crystalline quality. Herein, lithium polyacrylate (LiPAA) was utilized as a dual‐functional source and an in‐situ polymerization followed by a spray‐drying method was employed to synthesize Li3VO4. LiPAA serves a dual purpose, acting as both a lithium source to improve the crystal process and a carbon source to confine the particle size within a desired volume during high‐temperature treatment. Additionally, the in‐situ synthesis of a porous carbon decorating skeleton prevents the growth and agglomeration of Li3VO4 particles and provides abundant ion/electron diffusion channels and contact areas. Based on the synthesis route and the constructed primary‐secondary structure, the Li3VO4 anodes obtained in this study exhibit an impressive capacity of 596.2 mAh g−1. Moreover, they demonstrate enhanced rate performance over 600 cycles during 10 periods of rate testing, as well as a remarkably long lifespan of 5000 cycles at high currents. The utilization of LiPAA as a dual‐functional source represents a broad approach that holds great potential for future research on high‐performance electrodes requiring both lithium and carbon sources.
Funder
National Natural Science Foundation of China
Higher Education Discipline Innovation Project
Subject
General Energy,General Materials Science,General Chemical Engineering,Environmental Chemistry