One‐pot Unsymmetrical Ketone Synthesis Employing a Pyrrole‐Bearing Formal Carbonyl Dication Linchpin Reagent
Author:
Affiliation:
1. Department of Chemistry, Willamette University, Salem, OR 97301 (USA)
2. Department of Chemistry, University of California, Berkeley, CA 94720 (USA)
Funder
National Science Foundation
Publisher
Wiley
Subject
General Chemistry,Catalysis
Link
https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.201502894
Reference42 articles.
1. Palladium-catalyzed carbonylative coupling reactions between Ar–X and carbon nucleophiles
2. A highly efficient synthetic route to ketones through sequential coupling reactions of grignard reagents with -phenyl carbonochloridothioate in the presence of nickel or iron catalysts
3. Tandem-Bisalkylation of 2-Trialkylsilyl-1,3-dithiane: A New Sequential Transformation for the Synthesis of C2-Symmetrical Enantiopure 1,5-Diols and β,β′-Dihydroxyketones as well as of Enantiopure 1,3,5-Triols
4. Multicomponent Linchpin Couplings of Silyl Dithianes via Solvent-Controlled Brook Rearrangement
5. For overviews of this tactic see:
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