Mixed colors by combustion of mixed homogeneous pyrotechnics and heterogeneous charges

Author:

Bouma Richard H. B.1ORCID,Kotter Lance N.2ORCID,Smit Wouter J. L.1,Zebregs Martijn1,Groven Lori J.3ORCID

Affiliation:

1. Department of Energetic Materials the Netherlands Organization for Applied Scientific Research P.O. Box 480 2501 CL The Hague The Netherlands

2. Department of Materials Engineering and Science South Dakota School of Mines and Technology 501 E Saint Joseph St. Rapid City SD, 57701 US

3. Department of Chemical and Biological Engineering South Dakota School of Mines and Technology, 501 E Saint Joseph St. Rapid City SD, 57701 US

Abstract

AbstractThe combustion of mixed homogeneous pyrotechnic compositions and heterogeneous charges is studied experimentally with the aim of producing a selectable wavelength signal flare. The heterogeneous charge was perceived as a mixed color by a distant observer. A model for color chromaticity coordinates of homogeneous mixtures was derived that includes the mass, mass‐based burn rate and luminous intensity ratios of the constituting color compositions. This model can predict the expected dominant wavelength of a mixed composition. It can also handle the spacing of chromaticity coordinates of mixed compositions on a straight line in the CIE diagram between chromaticity coordinates of constituting colors. With two series of color composition mixtures, it was demonstrated that the chromaticity coordinates of the mixtures could be at, or slightly deviate, from the straight line connecting the chromaticity coordinates of the constituting compositions. It indicates there is little to no influence of flame temperature and mutual pyrotechnic reactions.

Funder

U.S. Department of Defense

Publisher

Wiley

Subject

General Chemical Engineering,General Chemistry

Reference18 articles.

1. K. L. Kosanke B. J.Kosanke The Chemistry of Colored Flame Pyrotechnic Chemistry 2004.

2. Novel colored flames via chromaticity of essential colors

3. High Color Purity Low Smoke Solvent-free Multi-color Signal Flares (serdp-estcp.org).

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