Ignition and energy release performance of dual‐oxidant Al/MnO2/CuO ternary thermites under rapid heating conditions

Author:

Liu Zhaohu1,He Chuan1ORCID,Zhuang Zhihua1,Li Shukui123,Feng Xinya1,Liu Jinxu12

Affiliation:

1. School of Materials Science and Engineering Beijing Institute of Technology Beijing 100081 China

2. China National Key Laboratory of Science and Technology on Materials under Shock and Impact Beijing Institute of Technology Beijing 100081 China

3. Department of Materials Science and Engineering Shenzhen MSU-BIT University Shenzhen 518172 China

Abstract

AbstractTailoring the energy release performance of the thermites is crucial for their application in various fields. In this article, dual‐oxidant Al/MnO2/CuO ternary thermites with varying compositions were prepared and systematically evaluated. The ignition delay time, heat of reaction, self‐sustained burning rate, and pressure performance of the thermites were evaluated. As the Al/CuO content increased, the ignition delay time and heat of reaction decreased, while the reaction efficiency, burning rate, pressure peak, and pressurization rate increased. Furthermore, the synergistic addition of the MnO2 and CuO led to enhanced relative flame intensity and maximum flame temperature in the ternary thermite. Our work demonstrates an effective strategy for regulating the energy performance of the thermites by co‐adding of metal oxides. This approach opens avenues for tailoring thermite properties to meet the diverse requirements of various applications.

Funder

National Natural Science Foundation of China

Publisher

Wiley

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