A novel n‐UV convertible colour‐tunable emitting oxynitride phosphor: Realization based on Ce3+‐Tb3+ energy transfer

Author:

You Huanhuan1,Huang Xiaoyu1,Zhang Xingda1,Jin Piaopiao1,Xu Zhaopeng2,Zhai Jing1,Gao Faming1,Jia Yongchao1ORCID

Affiliation:

1. Hebei Key Laboratory of Applied Chemistry Yanshan University Hebei Street 438 Qinhuangdao China

2. The Key Laboratory for Special Fiber and Fiber Sensor of Hebei Province, School of Information Science and Engineering Yanshan University Qinhuangdao China

Abstract

AbstractIn the present work, a novel n‐UV convertible colour‐tunable emitting phosphor was obtained based on the efficient Ce3+‐Tb3+ energy transfer in the Y10Al2Si3O18N4 host. By properly controlling the ratio of Ce3+/Tb3+, the colour hue of the obtained powder covered the blue and green regions, under excitation of 365 nm. The steady‐state and dynamic‐state luminescence measurement was performed to shed light on the related mechanism, which was justified by the electronic dipole–quadrupole dominating the related energy transfer process. Preliminary studies showed that Y10Al2Si3O18N4:Ce3+,Tb3+ can be promising as an inorganic phosphor for white LED applications.

Funder

National Key Research and Development Program of China

Natural Science Foundation of Hebei Province

Publisher

Wiley

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