Visible <scp><b>Light‐Driven Catalyst‐Free</b></scp> Amination of Indoles Initiated by Electron <scp><b>Donor‐Acceptor</b></scp> Complexes-Reference-Cited by-同舟云学术

Visible Light‐Driven Catalyst‐Free Amination of Indoles Initiated by Electron Donor‐Acceptor Complexes

Published:2023-03-25 Issue:12 Volume:41 Page:1485-1490
ISSN:1001-604X
Container-title:Chinese Journal of Chemistry
language:en
Short-container-title:Chin. J. Chem.

Author:

Sui Jiahong¹,Yang Zhonglie¹,Li Shuangqiao¹,Chen Xueqin¹,Zhang Xiaobin¹,Shen Qing²,Jiang Hezhong¹,Li Jiahong¹

Affiliation:

1. School of Life Science and Engineering, Sichuan Engineering Research Center for Biomimetic Synthesis of Natural Drugs Southwest Jiaotong University Chengdu Sichuan 610031 China

2. Department of Pharmacy, Sichuan Academy of Medical Science & Sichuan Provincial People's Hospital/Personalized Drug Therapy Key Laboratory of Sichuan Province, School of Medicine University of Electronic Science and Technology of China Chengdu Sichuan 610072 China

Abstract

Comprehensive SummaryThe visible light‐driven C2 or C3 amination of indoles without any additives was initiated via electron donor‐acceptor (EDA) complex formed by indole and N‐aminopyridinium salt. This method was compatible with a wide range of substrates and could proceed smoothly without the addition of any photocatalysts, transition‐metal catalysts, or bases. A variety of studies were carried out to examine the presence of EDA complex.

Funder

Sichuan Provincial Administration of Traditional Chinese Medicine

Publisher

Wiley

Subject

General Chemistry

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/cjoc.202200772

Reference54 articles.

1. Transition-Metal-Catalyzed C–N Bond Forming Reactions Using Organic Azides as the Nitrogen Source: A Journey for the Mild and Versatile C–H Amination

2. C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed oxidative C–H activation

3. Lamellarins and Related Pyrrole-Derived Alkaloids from Marine Organisms