Perylene Diimide Incorporated Polyurethane Polymer as Potential Colour Filter Material with Non‐fluorescent Property†

Abstract

Comprehensive SummaryA novel polyurethane polymer containing perylene diimide (PDI) unit and aniline segment, denoted as PU‐PDI, was designed and synthesized. Their tensile property and photophysical characteristic were investigated using various experimental and theoretical techniques. It is found that the elongation of PU‐PDIs can reach more than 1000%, indicating good tensile performance. Moreover, based on the photoinduced electron transfer mechanism, the aniline segments in polyurethane can quench the auto‐fluorescence of PDI unit to a negligible value, which overcomes the intractable fluorescence drawbacks of conventional colour filters. The non‐emissive characteristic, in combination with the good thermal stability and tensile property of PU‐PDI, provides a feasible design strategy to fabricate optical filters with high display quality.