Affiliation:
1. Key Laboratory for Green Organic Synthesis and Application of Hunan Province, Key Laboratory of Environmentally Friendly Chemistry and Application of Ministry of Education, College of Chemistry Xiangtan University Xiangtan Hunan 411105 China
2. Department School of Chemistry and Chemical Engineering Henan Normal University Xinxiang Henan 453007 China
Abstract
Comprehensive SummaryA general and broadly applicable copper and photoredox dual‐catalyzed multicomponent 1,4‐perfluoroalkylcyanation of 1,3‐enynes has been developed. This protocol enjoys success with high regioselectivity, mild reaction conditions, and excellent functional‐group tolerance, allowing the facile synthesis of structurally diverse perfluoroalkylated allenes from readily available fluoroalkyl halides, 1,3‐enynes and TMSCN in a one‐pot manner. A reasonable mechanism has been proposed according to a series of control experiments.
Funder
National Natural Science Foundation of China
Hunan Provincial Innovation Foundation for Postgraduate
Hunan Provincial Natural Science Foundation
Cited by
1 articles.
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