Ru(<scp>II</scp>)‐Catalyzed <i>ortho</i> C—H Allylation of <scp><i>N</i>‐Aryl</scp>‐7‐azaindoles with <scp>2‐Methylidene</scp> Cyclic Carbonate-Reference-Cited by-同舟云学术

Ru(II)‐Catalyzed ortho C—H Allylation of N‐Aryl‐7‐azaindoles with 2‐Methylidene Cyclic Carbonate

Published:2024-01-22 Issue: Volume: Page:
ISSN:1001-604X
Container-title:Chinese Journal of Chemistry
language:en
Short-container-title:Chin. J. Chem.

Author:

Zhang Jing¹,Luo Quan‐Jian¹,Wang Han‐Chi¹,Li Jin‐Heng¹²³,Sun Bo¹

Affiliation:

1. State Key Laboratory Base of Eco‐Chemical Engineering, College of Chemical Engineering Qingdao University of Science and Technology Qingdao Shandong 266042 China

2. State Key Laboratory of Applied Organic Chemistry Lanzhou University Lanzhou Gansu 730000 China

3. School of Chemistry and Chemical Engineering Henan Normal University Xinxiang Henan 453007 China

Abstract

Comprehensive SummaryA Ru(II)‐catalyzed ortho allylation reaction of N‐aryl‐7‐azaindole with readily available 2‐methylidene cyclic carbonate has been developed. This reaction is an effective pathway for synthesizing 7‐azaindole derivatives with a wide scope of substrates and high yields. In addition, the method can be extended to the allylation of other heterocyclic compounds and several cyclic carbonates, highlighting the practicality of this strategy for synthesis.

Funder

Natural Science Foundation of Shandong Province

Publisher

Wiley

Subject

General Chemistry

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/cjoc.202300627

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