Nickel(<scp>II</scp>)‐Catalyzed Reductive Coupling of Xanthate Esters with Sulfur‐Containing and Selenium‐Containing Compounds: Synthesis of Unsymmetric Sulfides and Selenides-Reference-Cited by-同舟云学术

Nickel(II)‐Catalyzed Reductive Coupling of Xanthate Esters with Sulfur‐Containing and Selenium‐Containing Compounds: Synthesis of Unsymmetric Sulfides and Selenides

Published:2024-06-03 Issue: Volume: Page:
ISSN:1001-604X
Container-title:Chinese Journal of Chemistry
language:en
Short-container-title:Chin. J. Chem.

Author:

Han Jia‐Hui¹,Sheng Daopeng²³,Chen Yi‐Rong¹,Shuai Xiao‐Yue¹,Rao Weidong²,Shen Shu‐Su⁴,Wang Shun‐Yi¹

Affiliation:

1. Key Laboratory of Organic Synthesis of Jiangsu Province College of Chemistry, Chemical Engineering and Materials Science & Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University Suzhou Jiangsu 215123 China

2. Key Laboratory of Biomass‐based Green Fuels and Chemicals College of Chemical Engineering, Nanjing Forestry University Nanjing Jiangsu 210037 China

3. State Key Laboratory of Radiation Medicine and Protection School for Radiological and Interdisciplinary Sciences (RAD‐X) and Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education Institutions, Soochow University Suzhou Jiangsu 215123 China

4. School of Environmental Science and Engineering Suzhou University of Science and Technology No. 99, Xuefu Road, Huqiu District Suzhou Jiangsu 215009 China

Abstract

Comprehensive SummaryUnsymmetric sulfides and selenides have great applications in the pharmaceutical field. Herein, we describe the reductive coupling reaction of xanthate esters with sulfur‐containing and selenium‐containing compounds (thio(seleno)sulfonates and disulfides(selenides)) under the nickel‐catalyzed condition. It provides a mild and effective method for the synthesis of unsymmetric sulfides and selenides which has the advantages of mild reaction conditions, high yields and a wide range of substrates.

Funder

National Natural Science Foundation of China

Publisher

Wiley

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/cjoc.202400326

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