Radiation‐induced corrosion model for copper‐coated used fuel containers. Part 1. Validation of the bulk radiolysis submodel

Author:

Behazin Mehran1ORCID,Briggs Scott1ORCID,King Fraser2ORCID

Affiliation:

1. Nuclear Waste Management Organization Toronto Ontario Canada

2. Integrity Corrosion Consulting Ltd. Nanaimo British Columbia Canada

Abstract

AbstractThis paper describes the development of a mixed‐potential model coupling the anodic dissolution of copper to the oxidation and reduction of various radiolysis products, allowing the long‐term prediction of the radiation‐induced corrosion of copper. The overall conceptual model is described, followed by a more detailed discussion of the use of the commercial COMSOL software to predict bulk radiolysis behavior. Various methods are used to validate the COMSOL bulk radiolysis model, including comparison with short‐term experimental data reported in the literature. The underlying principles and assumptions along with the results of the validation procedures are also presented.

Funder

Nuclear Waste Management Organization

Publisher

Wiley

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,Mechanical Engineering,Mechanics of Materials,Environmental Chemistry,Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,Mechanical Engineering,Mechanics of Materials,Environmental Chemistry,Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,Mechanical Engineering,Mechanics of Materials,Environmental Chemistry

Reference36 articles.

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2. The corrosion behaviour of candidate container materials for the disposal of high-level waste and spent fuel – a summary of the state of the art and opportunities for synergies in future R&D

3. Swedish Corrosion Institute Kärnbränslesäkerhet Technical Report KBS‐TR‐90 Stockholm 1978.

4. Kärnbränslesäkerhet  KBS 2 ‐ Handling and Final Storage of Unreprocessed Spent Nuclear Fuel II ‐ Technical; KBS 720‐2 Stockholm 1978.

5. F.King Ontario Power Generation Nuclear Waste Management Division Report Report No. 06819‐REP‐01300‐10101 Toronto 2005.

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