Wet H2S corrosion and degradation of pipeline in amine regeneration system

Author:

Orlikowski Juliusz1,Kalinowski Maciej2,Lasota Igor2,Maruszewski Piotr2,Szocinski Michal1ORCID,Darowicki Kazimierz1

Affiliation:

1. Department of Electrochemistry, Corrosion and Materials Engineering, Faculty of Chemistry Gdansk University of Technology Gdansk Poland

2. ORLEN S.A. Plock Poland

Abstract

AbstractThe paper presents the results of non‐destructive testing examinations, metallographic tests and risk assessment of degradation related to corrosion of amine regeneration unit in a desulphurisation system. Intensive corrosion resulting from acid gases environment upon water condensation causes perforation of the pipeline. Detailed analysis reveals cracking related to the mechanism of wet H2S. Hydrogen penetration, resulting from the wet H2S process, causes a decrease in mechanical properties of steel and an increase in hydrogen content inside steel. Corrosion results mostly from high stream velocity, the presence of acid gases (with high ammonia content), the presence of amine and low stream temperature.

Publisher

Wiley

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,Mechanical Engineering,Mechanics of Materials,Environmental Chemistry,Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,Mechanical Engineering,Mechanics of Materials,Environmental Chemistry,Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,Mechanical Engineering,Mechanics of Materials,Environmental Chemistry

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