A highly sensitive spectrofluorimetric method for the determination of bilastine in human plasma: Application of content uniformity testing

Author:

Omar Mahmoud A.12ORCID,Khojah Hani M. J.3,Al Thagfan Sultan S.3,Alolayan Sultan Othman3,Attia Tamer Z.2ORCID

Affiliation:

1. Department of Pharmacognosy and Pharmaceutical Chemistry College of Pharmacy Taibah University, Al‐Madinah Al‐Munawwarah Saudi Arabia

2. Analytical Chemistry Department, Faculty of Pharmacy Minia University Minia Egypt

3. Department of Pharmacy Practice College of Pharmacy Taibah University, Al‐Madinah Al‐Munawarah Saudi Arabia

Abstract

AbstractBilastine, a new second generation antihistaminic drug, has been widely used for relieving symptoms of allergic rhinitis and urticaria without a sedative effect. A simple, cost‐effective, and highly sensitive fluorimetric method was developed for the estimation of bilastine in human plasma, in addition to its pure state and tablets. The suggested method depended on binary complex formation of eosin with bilastine in a buffered medium at pH 4.2. The formed complex resulted in quantitative quenching of eosin emission at 538 nm after excitation at 335 nm. This method demonstrates a broad range of linearity, spanning from 200 to 1000 ng/mL, and exhibits exceptional sensitivity, with a limit of detection and quantitation of 30.85 and 93.48 ng/mL, respectively. In addition, this spectrofluorimetric method may be employed to determine the amount of bilastine in human plasma and tablets with satisfactory accuracy and excellent precision. Furthermore, the content uniformity of bilastine in commercially available tablets was successfully tested by this approach. Compared with the reference method, there were no significant variations in terms of precision or accuracy. In conclusion, the proposed protocol is highly recommended to quantitatively estimate bilastine in different quality control settings.

Publisher

Wiley

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