Difluorination at Boron Leads to the First Electrophilic Ligated Boryl Radical (NHC‐BF 2 . )-Reference-Cited by-同舟云学术

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Difluorination at Boron Leads to the First Electrophilic Ligated Boryl Radical (NHC‐BF 2 . )

Published:2018-07-18 Issue:32 Volume:130 Page:10408-10413
ISSN:0044-8249
Container-title:Angewandte Chemie
language:en
Short-container-title:Angew. Chem.

Author:

Subervie Daniel¹,Graff Bernadette²,Nerkar Swapnil³,Curran Dennis P.³,Lalevée Jacques²,Lacôte Emmanuel¹^ORCID

Affiliation:

1. Univ Lyon Université Claude Bernard Lyon 1 CNRS, CNES, ArianeGroup, LHCEP Bât. Raulin, 2 rue Victor Grignard 69622 Villeurbanne France

2. Institut de Science des Matériaux de Mulhouse (IS2M), UMR CNRS 7361 Université de Haute Alsace 15 rue Jean Starcky 68057 Mulhouse France

3. Department of Chemistry University of Pittsburgh Pittsburgh PA 15260 USA

Funder

Agence Nationale de la Recherche

National Science Foundation

Publisher

Wiley

Subject

General Medicine

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/ange.201806476

Reference55 articles.

1.

2. Homolytic reactions of ligated boranes. Part 17. Amine–boranes as polarity reversal catalysts for radical chain reactions of esters with vinylic epoxides and with allylic tert-butyl peroxides

3. Homolytic reactions of ligated boranes. Part 19. Relationships between structure, reactivity and enantioselectivity for hydrogen-atom abstraction by chiral amine–boryl radicals

4. Homolytic reactions of ligated boranes. Part 18. The scope of enantioselective hydrogen-atom abstraction by chiral amine–boryl radicals for kinetic resolution under conditions of polarity reversal catalysis

5. Polarity-reversal catalysis of hydrogen-atom abstraction reactions: concepts and applications in organic chemistry

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1. Persistent and Predominantly Localized Boron Radical from the Reduction of a Three‐Dimensional Analogue of NHC‐Stabilized Borafluorenium;Chemistry – A European Journal;2023-05-24

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